Octahedral Interstices

Adjacent to the Td hole, three atoms in the B layer touch three atoms in the A layer such that a trigonal antiprismatic polyhedron (a regular octahedron) is formed. At the center of the octahedron is a cavity called the Octahedral Hole (a common symbol for "octahedral" is Oh). A guest sphere will just fill this cavity and touch the six host spheres if its radius is approximately 0.41r. It can be shown that there are twice as many Td holes as there are Oh holes in any closest packed bilayer.

(crossed stereo pair)
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