Zinc Sulfide

The structure of cubic ZnS (mineral name "zinc blende") may be viewed as a CCP lattice of anions (Z = 4), with the smaller cations occupying every other Td hole (Z = 4) or vice versa.

(crossed stereo pair)

An equivalent description of this lattice is as interpenetrating FCC lattices of equal dimensions, one for the anions and one for the cations.

(crossed stereo pair)

Note that the other form of ZnS, wurtzite, is hexagonal, not cubic, and can be described as an HCP lattice of anions with cations in every other Td hole.

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