Crystal Lattice Structures
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Introduction

Simple Cubic

Body Centered Cubic

Face Centered Cubic

Primitive FCC

Simple Hexagonal

Hexagonal Closest Packing

HCP Coordination

Cubic Closest Packing

CCP Coordination

Rhombohedral

2- & 3-Layer repeats

4-layer repeats

Tetrahedral Holes

Octahedral Holes

CsCl

NaCl

Halite

Fluorite

Zinc Blende

Exercises

Octahedral Interstices
  Adjacent to the Td hole, three atoms in the B layer touch three atoms in the A layer such that a trigonal antiprismatic polyhedron (a regular octahedron) is formed. At the center of the octahedron is a cavity called the Octahedral Hole (a common symbol for "octahedral" is Oh). A guest sphere will just fill this cavity and touch the six host spheres if its radius is approximately 0.41r. It can be shown that there are twice as many Td holes as there are Oh holes in any closest packed bilayer. 

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Steven F. Watkins, Department of Chemistry, Louisiana State University