Crystal Lattice Structures
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Introduction

Simple Cubic

Body Centered Cubic

Face Centered Cubic

Primitive FCC

Simple Hexagonal

Hexagonal Closest Packing

HCP Coordination

Cubic Closest Packing

CCP Coordination

Rhombohedral

2- & 3-Layer repeats

4-layer repeats

Tetrahedral Holes

Octahedral Holes

CsCl

NaCl

Halite

Fluorite

Zinc Blende

Exercises

Zinc Sulfide
  The structure of cubic ZnS (mineral name "zinc blende") may be viewed as a CCP lattice of anions (Z = 4), with the smaller cations occupying every other Td hole (Z = 4) or vice versa.
An equivalent description of this lattice is as interpenetrating FCC lattices of equal dimensions, one for the anions and one for the cations.
Note that the other form of ZnS, wurtzite, is hexagonal, not cubic, and can be described as an HCP lattice of anions with cations in every other Td hole.
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Steven F. Watkins, Department of Chemistry, Louisiana State University